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Standard enthalpy change of vaporization

The standard enthalpy change of vaporization is a physical property of substances. It is defined as the amount of heat (or energy) required per unit mass of a substance to completely vaporize the substance at its boiling point. The heat of vaporization is expressed in kJ/mol, or calories/gram. The use of kJ/kg is also possible, but less customary. Other units still in use in certain places include Btu/lb.

Because vaporization is the opposite process of condensation, the term heat of condensation is also used. The latter is defined as the heat released when a unit mass of a substance is completely condensed at its boiling point.

The standard enthalpy change of vaporization of water is about 2260 kJ/kg which is equal to 40.8 kJ/mol. This is quite a lot: it is five times the energy needed for heating the water from 0 °C to 100 °C.

Contents

Heats of vaporization of the elements

Element Heat of vaporization (kJ/mol)
Actinium n/a
Aluminium 293.4
Antimony 77.14
Argon 6.447
Arsenic 34.76
Astatine 114
Barium 142
Beryllium 292.40
Bismuth 104.8
Boron 489.7
Bromine 15.438
Cadmium 100
Caesium 67.74
Calcium 153.6
Carbon 355.8
Cerium 414
Chlorine 10.2
Chromium 344.3
Cobalt 376.5
Copper 300.3
Fluorine 3.2698
Gallium 258.7
Germanium 330.9
Gold 334.4
Hafnium 575
Helium 0.0845
Element Heat of vaporization (kJ/mol)
Hydrogen 0.44936
Indium 231.5
Iodine 20.752
Iridium 604
Iron 349.6
Krypton 9.029
Lanthanum 414
Lead 177.7
Lithium 145.92
Magnesium 127.4
Manganese 226
Mercury 59.229
Molybdenum 598
Neon 1.7326
Neptunium n/a
Nickel 370.4
Niobium 696.6
Nitrogen 2.7928
Osmium 627.6
Oxygen 3.4099
Palladium 357
Phosphorus 12.129
Platinum 510
Polonium 60.1
Potassium 79.87
Radium 37
Element Heat of vaporization (kJ/mol)
Radon 16.4
Rhenium 715
Rhodium 493
Rubidium 72.216
Ruthenium 595
Scandium 314.2
Selenium 26.3
Silicon 384.22
Silver 250.58
Sodium 96.96
Strontium 144
Sulfur 1.7175
Tantalum 743
Technetium 660
Tellurium 52.55
Terbium ???
Thallium 164.1
Thorium 514.4
Tin 295.8
Titanium 421
Tungsten 824
Vanadium 452
Xenon 12.636
Yttrium 363
Zinc 115.3
Zirconium 58.2

Other common substances

Element Heat of vaporization (kJ/mol)
Methanol 37.4
Ammonia 23.35
Water 40.65
Methane 8.19
Phosphine 14.6
Propane 356 kJ/kg
Butane 362 kJ/kg

See also

Reference

Sears, Zemansky et. al., University Physics, Addison-Wessley Publishing Company, Sixth ed., 1982, ISBN 0-201-07199-1

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